The effect of S-alkylation on organocatalytic enamine activation through imidazolidine-4-thiones

Imidazolidine-4-thiones have been suggested as potential prebiotic organocatalysts for light-driven α-alkylations of aldehydes by bromoacetonitrile. However, imidazolidine-4-thiones react with bromoacetonitrile to give S-cyanomethylated dihydroimidazoles. Kinetic studies show that enamines derived f...

Descripción completa

Detalles Bibliográficos
Autores principales: Hensinger, Magenta J., Closs, Anna C., Trapp, Oliver, Ofial, Armin R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10297834/
https://www.ncbi.nlm.nih.gov/pubmed/37293771
http://dx.doi.org/10.1039/d3cc01912h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10297834/
https://www.ncbi.nlm.nih.gov/pubmed/37293771
http://dx.doi.org/10.1039/d3cc01912h

Ejemplares similares