Ligand Rigidity Steers the Selectivity and Efficiency of the Photosubstitution Reaction of Strained Ruthenium Polypyridyl Complexes

[Image: see text] While photosubstitution reactions in metal complexes are usually thought of as dissociative processes poorly dependent on the environment, they are, in fact, very sensitive to solvent effects. Therefore, it is crucial to explicitly consider solvent molecules in theoretical models o...

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Detalles Bibliográficos
Autores principales: Hakkennes, Matthijs L. A., Meijer, Michael S., Menzel, Jan Paul, Goetz, Anne-Charlotte, Van Duijn, Roy, Siegler, Maxime A., Buda, Francesco, Bonnet, Sylvestre
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10299800/
https://www.ncbi.nlm.nih.gov/pubmed/37294954
http://dx.doi.org/10.1021/jacs.3c03543

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10299800/
https://www.ncbi.nlm.nih.gov/pubmed/37294954
http://dx.doi.org/10.1021/jacs.3c03543

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