Cargando…

Ligand Rigidity Steers the Selectivity and Efficiency of the Photosubstitution Reaction of Strained Ruthenium Polypyridyl Complexes

[Image: see text] While photosubstitution reactions in metal complexes are usually thought of as dissociative processes poorly dependent on the environment, they are, in fact, very sensitive to solvent effects. Therefore, it is crucial to explicitly consider solvent molecules in theoretical models o...

Descripción completa

Detalles Bibliográficos
Autores principales:	Hakkennes, Matthijs L. A., Meijer, Michael S., Menzel, Jan Paul, Goetz, Anne-Charlotte, Van Duijn, Roy, Siegler, Maxime A., Buda, Francesco, Bonnet, Sylvestre
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2023
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10299800/ https://www.ncbi.nlm.nih.gov/pubmed/37294954 http://dx.doi.org/10.1021/jacs.3c03543

Ejemplares similares

Selective Preparation of a Heteroleptic Cyclometallated Ruthenium Complex Capable of Undergoing Photosubstitution of a Bidentate Ligand
por: Cuello‐Garibo, Jordi‐Amat, et al.
Publicado: (2018)

Diastereoselective Synthesis and Two-Step Photocleavage of Ruthenium Polypyridyl Complexes Bearing a Bis(thioether) Ligand
por: Meijer, Michael S., et al.
Publicado: (2019)

Influence of the Steric Bulk and Solvent on the Photoreactivity of Ruthenium Polypyridyl Complexes Coordinated to l-Proline
por: Cuello-Garibo, Jordi-Amat, et al.
Publicado: (2017)

Synthesis of O-1–O-6 Substituted Positional Isomers of d-Glucose–Thioether Ligands and Their Ruthenium Polypyridyl Conjugates
por: Lameijer, Lucien N., et al.
Publicado: (2018)

Alkyne Functionalization of a Photoactivated Ruthenium Polypyridyl Complex for Click-Enabled Serum Albumin Interaction Studies
por: Busemann, Anja, et al.
Publicado: (2020)

Photosubstitution in a trisheteroleptic ruthenium complex inhibits conjunctival melanoma growth in a zebrafish orthotopic xenograft model
por: Chen, Quanchi, et al.
Publicado: (2022)

Chemical Swarming: Depending on Concentration, an Amphiphilic Ruthenium Polypyridyl Complex Induces Cell Death via Two Different Mechanisms
por: Siewert, Bianka, et al.
Publicado: (2016)

Steric hindrance, ligand ejection and associated photocytotoxic properties of ruthenium(II) polypyridyl complexes
por: Herrera-Ramírez, Piedad, et al.
Publicado: (2023)

Effects of chirality on the intracellular localization of binuclear ruthenium(II) polypyridyl complexes
por: Svensson, Frida R., et al.
Publicado: (2012)

Correction: Chiral ruthenium polypyridyl complexes as mitochondria-targeted apoptosis inducers
por: Chen, Tianfeng, et al.
Publicado: (2018)

Recent Advances on Octahedral Polypyridyl Ruthenium(II) Complexes as Antimicrobial Agents
por: Yang, Yulin, et al.
Publicado: (2018)

Octahedral ruthenium (II) polypyridyl complexes as antimicrobial agents against mycobacterium
por: Liao, Guojian, et al.
Publicado: (2017)

Stabilization of Long-Looped i-Motif DNA by Polypyridyl Ruthenium Complexes
por: Pages, Benjamin J., et al.
Publicado: (2019)

Synthesis and Optimization of Mesoporous Silica Nanoparticles for Ruthenium Polypyridyl Drug Delivery
por: Harun, Siti Norain, et al.
Publicado: (2021)

A Mechanism Study of Redox Reactions of the Ruthenium-oxo-polypyridyl Complex
por: Chen, Bao-Long, et al.
Publicado: (2023)

Ruthenium-Locked Helical Chirality: A Barrier of Inversion and Formation of an Asymmetric Macrocycle
por: van de Griend, Corjan, et al.
Publicado: (2022)

Cellular and cell-free studies of catalytic DNA cleavage by ruthenium polypyridyl complexes containing redox-active intercalating ligands
por: Griffith, Cynthia, et al.
Publicado: (2017)

Red Light Activation of Ru(II) Polypyridyl Prodrugs via Triplet-Triplet Annihilation Upconversion: Feasibility in Air and through Meat
por: Askes, Sven H. C., et al.
Publicado: (2016)

Ultrafast transient IR spectroscopy and DFT calculations of ruthenium(ii) polypyridyl complexes
por: Sun, Qinchao, et al.
Publicado: (2017)

Evaluation of the In Vitro and In Vivo Efficacy of Ruthenium Polypyridyl Compounds against Breast Cancer
por: Lenis-Rojas, Oscar A., et al.
Publicado: (2021)

New ruthenium polypyridyl complexes as potential sensors of acetonitrile and catalysts for water oxidation
por: Abate, Pedro O., et al.
Publicado: (2022)

Ruthenium Polypyridyl Complex Bound to a Unimolecular Chair-Form G-Quadruplex
por: McQuaid, Kane T., et al.
Publicado: (2022)

Ruthenium-Based Photoactivated Chemotherapy
por: Bonnet, Sylvestre
Publicado: (2023)

Ruthenium(II) Polypyridyl Complexes Containing Simple Dioxo Ligands: a Structure‐Activity Relationship Study Shows the Importance of the Charge
por: Gandioso, Albert, et al.
Publicado: (2022)

Targeting the endoplasmic reticulum with a membrane-interactive luminescent ruthenium(ii) polypyridyl complex
por: Gill, Martin R., et al.
Publicado: (2013)

Designing photolabile ruthenium polypyridyl crosslinkers for hydrogel formation and multiplexed, visible-light degradation
por: Rapp, Teresa L., et al.
Publicado: (2019)

Ruthenium(II) Polypyridyl Complexes and Their Use as Probes and Photoreactive Agents for G-quadruplexes Labelling
por: Jiang, Julie, et al.
Publicado: (2022)

A Ruthenium(II) Polypyridyl Complex Disrupts Actin Cytoskeleton Assembly and Blocks Cytokinesis
por: Gill, Martin R., et al.
Publicado: (2022)

To cage or to be caged? The cytotoxic species in ruthenium-based photoactivated chemotherapy is not always the metal
por: Cuello-Garibo, Jordi-Amat, et al.
Publicado: (2017)

Unusual Water Oxidation Mechanism via a Redox-Active Copper Polypyridyl Complex
por: den Boer, Daan, et al.
Publicado: (2023)

Disruption of microtubule function in cultured human cells by a cytotoxic ruthenium(ii) polypyridyl complex
por: Alatrash, Nagham, et al.
Publicado: (2019)

Reactivity of non-organometallic ruthenium(II) polypyridyl complexes and their application as catalysts for hydride transfer reactions
por: Chrzanowska, Marta, et al.
Publicado: (2023)

Ruthenium-based PACT agents based on bisquinoline chelates: synthesis, photochemistry, and cytotoxicity
por: Busemann, Anja, et al.
Publicado: (2021)

796 nm Activation of a Photocleavable Ruthenium(II) Complex Conjugated to an Upconverting Nanoparticle through Two Phosphonate Groups
por: Meijer, Michael S., et al.
Publicado: (2020)

Ruthenium polypyridyl complexes and their modes of interaction with DNA: Is there a correlation between these interactions and the antitumor activity of the compounds?
por: Corral, Eva, et al.
Publicado: (2008)

Ruthenium(II) Polypyridyl Complexes for Antimicrobial Photodynamic Therapy: Prospects for Application in Cystic Fibrosis Lung Airways
por: Youf, Raphaëlle, et al.
Publicado: (2022)

Good Vibrations Report on the DNA Quadruplex Binding of an Excited State Amplified Ruthenium Polypyridyl IR Probe
por: Stitch, Mark, et al.
Publicado: (2023)

Ruthenium(II) Polypyridyl Complexes as FRET Donors: Structure- and Sequence-Selective DNA-Binding and Anticancer Properties
por: Elgar, Christopher E., et al.
Publicado: (2023)

Chiral Ruthenium(II) Polypyridyl Complexes: Stabilization of G-Quadruplex DNA, Inhibition of Telomerase Activity and Cellular Uptake
por: Yu, Qianqian, et al.
Publicado: (2012)

Ruthenium(ii)-polypyridyl zirconium(iv) metal–organic frameworks as a new class of sensitized solar cells
por: Maza, W. A., et al.
Publicado: (2016)

Cannot write session to /tmp/vufind_sessions/sess_tgg4uuovhhf6p00naj82oefjhm