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Ag(2)(0) dimers within a thioether-functionalized MOF catalyze the CO(2) to CH(4) hydrogenation reaction
Ultrasmall silver clusters in reduced state are difficult to synthesize since silver atoms tend to rapidly aggregate into bigger entities. Here, we show that dimers of reduced silver (Ag(2)) are formed within the framework of a metal–organic framework provided with thioether arms in their walls (met...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10300047/ https://www.ncbi.nlm.nih.gov/pubmed/37369737 http://dx.doi.org/10.1038/s41598-023-37600-4 |