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Ag(2)(0) dimers within a thioether-functionalized MOF catalyze the CO(2) to CH(4) hydrogenation reaction

Ultrasmall silver clusters in reduced state are difficult to synthesize since silver atoms tend to rapidly aggregate into bigger entities. Here, we show that dimers of reduced silver (Ag(2)) are formed within the framework of a metal–organic framework provided with thioether arms in their walls (met...

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Detalles Bibliográficos
Autores principales: Zheng, Yongkun, Martín, Nuria, Boronat, Mercedes, Ferrando-Soria, Jesús, Mon, Marta, Armentano, Donatella, Pardo, Emilio, Leyva-Pérez, Antonio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10300047/
https://www.ncbi.nlm.nih.gov/pubmed/37369737
http://dx.doi.org/10.1038/s41598-023-37600-4