Asymmetric gradient orbital interaction of hetero-diatomic active sites for promoting C − C coupling

Diatomic-site catalysts (DACs) garner tremendous attention for selective CO(2) photoreduction, especially in the thermodynamical and kinetical mechanism of CO(2) to C(2+) products. Herein, we first engineer a novel Zn-porphyrin/RuCu-pincer complex DAC (ZnPor-RuCuDAC). The heteronuclear ZnPor-RuCuDAC...

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Detalles Bibliográficos
Autores principales: Wang, Jin Ming, Zhu, Qin Yao, Lee, Jeong Heon, Woo, Tae Gyun, Zhang, Yue Xing, Jang, Woo-Dong, Kim, Tae Kyu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10300110/
https://www.ncbi.nlm.nih.gov/pubmed/37369676
http://dx.doi.org/10.1038/s41467-023-39580-5

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10300110/
https://www.ncbi.nlm.nih.gov/pubmed/37369676
http://dx.doi.org/10.1038/s41467-023-39580-5

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