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Asymmetric gradient orbital interaction of hetero-diatomic active sites for promoting C − C coupling
Diatomic-site catalysts (DACs) garner tremendous attention for selective CO(2) photoreduction, especially in the thermodynamical and kinetical mechanism of CO(2) to C(2+) products. Herein, we first engineer a novel Zn-porphyrin/RuCu-pincer complex DAC (ZnPor-RuCuDAC). The heteronuclear ZnPor-RuCuDAC...
Autores principales: | Wang, Jin Ming, Zhu, Qin Yao, Lee, Jeong Heon, Woo, Tae Gyun, Zhang, Yue Xing, Jang, Woo-Dong, Kim, Tae Kyu |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10300110/ https://www.ncbi.nlm.nih.gov/pubmed/37369676 http://dx.doi.org/10.1038/s41467-023-39580-5 |
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