Selective C–H Bond Cleavage with a High-Spin Fe(IV)–Oxido Complex

Non-heme Fe monooxygenases activate C–H bonds using intermediates with high-spin Fe(IV)–oxido centers. To mimic these sites, a new tripodal ligand [pop](3−) was prepared that contains three phosphoryl amido groups that are capable of stabilizing metal centers in high oxidation states. The ligand was...

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Detalles Bibliográficos
Autores principales: Sun, Chen, Jaimes, Jennifer L., Follmer, Alec H., Ziller, Joseph W., Borovik, Andrew S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10301140/
https://www.ncbi.nlm.nih.gov/pubmed/37375309
http://dx.doi.org/10.3390/molecules28124755

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10301140/
https://www.ncbi.nlm.nih.gov/pubmed/37375309
http://dx.doi.org/10.3390/molecules28124755

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