Revision of the Peniroquesine Biosynthetic Pathway by Retro-Biosynthetic Theoretical Analysis: Ring Strain Controls the Unique Carbocation Rearrangement Cascade

[Image: see text] Peniroquesine, a sesterterpenoid featuring a unique 5/6/5/6/5 fused pentacyclic ring system, has been known for a long time, but its biosynthetic pathway/mechanism remains elusive. Based on isotopic labeling experiments, a plausible biosynthetic pathway to peniroquesines A–C and th...

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Detalles Bibliográficos
Autores principales: Matsuyama, Taro, Togashi, Ko, Nakano, Moe, Sato, Hajime, Uchiyama, Masanobu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10301677/
https://www.ncbi.nlm.nih.gov/pubmed/37388688
http://dx.doi.org/10.1021/jacsau.3c00039

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10301677/
https://www.ncbi.nlm.nih.gov/pubmed/37388688
http://dx.doi.org/10.1021/jacsau.3c00039

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