Enantioselective Catalysis with Pyrrolidinyl Gold(I) Complexes: DFT and NEST Analysis of the Chiral Binding Pocket

[Image: see text] A new generation of chiral gold(I) catalysts based on variations of complexes with JohnPhos-type ligands with a remote C(2)-symmetric 2,5-diarylpyrrolidine have been synthesized with different substitutions at the top and bottom aryl rings: from replacing the phosphine by a N-heter...

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Detalles Bibliográficos
Autores principales: Zuccarello, Giuseppe, Nannini, Leonardo J., Arroyo-Bondía, Ana, Fincias, Nicolás, Arranz, Isabel, Pérez-Jimeno, Alba H., Peeters, Matthias, Martín-Torres, Inmaculada, Sadurní, Anna, García-Vázquez, Víctor, Wang, Yufei, Kirillova, Mariia S., Montesinos-Magraner, Marc, Caniparoli, Ulysse, Núñez, Gonzalo D., Maseras, Feliu, Besora, Maria, Escofet, Imma, Echavarren, Antonio M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10301678/
https://www.ncbi.nlm.nih.gov/pubmed/37388697
http://dx.doi.org/10.1021/jacsau.3c00159

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10301678/
https://www.ncbi.nlm.nih.gov/pubmed/37388697
http://dx.doi.org/10.1021/jacsau.3c00159

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