Sparteine-Free, Highly Stereoselective Construction of Complex Allylic Alcohols Using 1,2-Metallate Rearrangements

[Image: see text] Stereotriads bearing allylic alcohols are privileged structures in natural products, and new methods accessing these in a stereoselective fashion are highly sought after. Toward this goal, we found that the use of chiral polyketide fragments allows for performing the Hoppe–Matteson...

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Detalles Bibliográficos
Autores principales: Linne, Yannick, Birkner, Maike, Flormann, Jan, Lücke, Daniel, Becker, Jörg August, Kalesse, Markus
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10301690/
https://www.ncbi.nlm.nih.gov/pubmed/37388702
http://dx.doi.org/10.1021/jacsau.3c00114

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10301690/
https://www.ncbi.nlm.nih.gov/pubmed/37388702
http://dx.doi.org/10.1021/jacsau.3c00114

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