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Unraveling the Bonding Complexity of Polyhalogen Anions: High-Pressure Synthesis of Unpredicted Sodium Chlorides Na(2)Cl(3) and Na(4)Cl(5) and Bromide Na(4)Br(5)
[Image: see text] The field of polyhalogen chemistry, specifically polyhalogen anions (polyhalides), is rapidly evolving. Here, we present the synthesis of three sodium halides with unpredicted chemical compositions and structures (tP10-Na(2)Cl(3), hP18-Na(4)Cl(5), and hP18-Na(4)Br(5)), a series of...
Autores principales: | , , , , , , , , , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10302743/ https://www.ncbi.nlm.nih.gov/pubmed/37388691 http://dx.doi.org/10.1021/jacsau.3c00090 |