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Unraveling the Bonding Complexity of Polyhalogen Anions: High-Pressure Synthesis of Unpredicted Sodium Chlorides Na(2)Cl(3) and Na(4)Cl(5) and Bromide Na(4)Br(5)

[Image: see text] The field of polyhalogen chemistry, specifically polyhalogen anions (polyhalides), is rapidly evolving. Here, we present the synthesis of three sodium halides with unpredicted chemical compositions and structures (tP10-Na(2)Cl(3), hP18-Na(4)Cl(5), and hP18-Na(4)Br(5)), a series of...

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Detalles Bibliográficos
Autores principales: Yin, Yuqing, Aslandukova, Alena, Jena, Nityasagar, Trybel, Florian, Abrikosov, Igor A., Winkler, Bjoern, Khandarkhaeva, Saiana, Fedotenko, Timofey, Bykova, Elena, Laniel, Dominique, Bykov, Maxim, Aslandukov, Andrey, Akbar, Fariia I., Glazyrin, Konstantin, Garbarino, Gaston, Giacobbe, Carlotta, Bright, Eleanor L., Jia, Zhitai, Dubrovinsky, Leonid, Dubrovinskaia, Natalia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10302743/
https://www.ncbi.nlm.nih.gov/pubmed/37388691
http://dx.doi.org/10.1021/jacsau.3c00090