PCP Pincer Complexes of Titanium in the +3 and +4 Oxidation States

[Image: see text] Ti(IV) and Ti(III) complexes using the (tBu)PCP ligand have been synthesized ((tBu)PCP = C(6)H(3)-2,6-(CH(2)P(t)Bu(2))(2)). The [(tBu)PCP]Li synthon can be reacted with TiCl(4)(THF)(2) to form ((tBu)PCP)TiCl(3) (1) in limited yields due to significant reduction of the titanium synt...

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Detalles Bibliográficos
Autores principales: Stadler, Benedek, Meng, Hilary H. Y., Belazregue, Sara, Webster, Leah, Collauto, Alberto, Byrne, Keelan M., Krämer, Tobias, Chadwick, F. Mark
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10302872/
https://www.ncbi.nlm.nih.gov/pubmed/37388272
http://dx.doi.org/10.1021/acs.organomet.2c00662

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10302872/
https://www.ncbi.nlm.nih.gov/pubmed/37388272
http://dx.doi.org/10.1021/acs.organomet.2c00662

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