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PCP Pincer Complexes of Titanium in the +3 and +4 Oxidation States
[Image: see text] Ti(IV) and Ti(III) complexes using the (tBu)PCP ligand have been synthesized ((tBu)PCP = C(6)H(3)-2,6-(CH(2)P(t)Bu(2))(2)). The [(tBu)PCP]Li synthon can be reacted with TiCl(4)(THF)(2) to form ((tBu)PCP)TiCl(3) (1) in limited yields due to significant reduction of the titanium synt...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10302872/ https://www.ncbi.nlm.nih.gov/pubmed/37388272 http://dx.doi.org/10.1021/acs.organomet.2c00662 |