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Fully Reduced and Mixed-Valent Multi-Copper Aggregates Supported by Tetradentate Diamino Bis(thiolate) Ligands

[Image: see text] Tetradentate diamino bis(thiolate) ligands (l-N(2)S(2)(2−)) with saturated linkages between heteroatoms support fully reduced [(Cu(l-N(2)S(2)))(2)Cu(2)] complexes that bear relevance as an entry point toward molecules featuring the Cu(2)(I)Cu(2)(II)(μ(4)-S) core composition of nitr...

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Detalles Bibliográficos
Autores principales: Wang, Bo, Barnes, Justin, Ferrara, Skylar J., Sproules, Stephen, Zhang, Xiaodong, Mague, Joel T., Donahue, James P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10302893/
https://www.ncbi.nlm.nih.gov/pubmed/37310001
http://dx.doi.org/10.1021/acs.inorgchem.3c00784