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Boron-Based Inverse Sandwich V(2)B(7)(−) Cluster: Double π/σ Aromaticity, Metal–Metal Bonding, and Chemical Analogy to Planar Hypercoordinate Molecular Wheels

Inverse sandwich clusters composed of a monocyclic boron ring and two capping transition metal atoms are interesting alloy cluster systems, yet their chemical bonding nature has not been sufficiently elucidated to date. We report herein on the theoretical prediction of a new example of boron-based i...

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Detalles Bibliográficos
Autores principales: Han, Peng-Fei, Sun, Qiang, Zhai, Hua-Jin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10305064/
https://www.ncbi.nlm.nih.gov/pubmed/37375276
http://dx.doi.org/10.3390/molecules28124721