Cargando…

Boron-Based Inverse Sandwich V(2)B(7)(−) Cluster: Double π/σ Aromaticity, Metal–Metal Bonding, and Chemical Analogy to Planar Hypercoordinate Molecular Wheels

Inverse sandwich clusters composed of a monocyclic boron ring and two capping transition metal atoms are interesting alloy cluster systems, yet their chemical bonding nature has not been sufficiently elucidated to date. We report herein on the theoretical prediction of a new example of boron-based i...

Descripción completa

Detalles Bibliográficos
Autores principales:	Han, Peng-Fei, Sun, Qiang, Zhai, Hua-Jin
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2023
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10305064/ https://www.ncbi.nlm.nih.gov/pubmed/37375276 http://dx.doi.org/10.3390/molecules28124721

Ejemplares similares

Chemical bonding and dynamic structural fluxionality of a boron-based Al(2)B(8) binary cluster: the robustness of a doubly 6π/6σ aromatic [B(8)](2−) molecular wheel
por: Yue, Rong-Xin, et al.
Publicado: (2023)

On the Nature of σ–σ, σ–π, and π–π Stacking in Extended Systems
por: Cabaleiro-Lago, Enrique M., et al.
Publicado: (2018)

Searching for double σ- and π-aromaticity in borazine derivatives
por: Pino-Rios, Ricardo, et al.
Publicado: (2020)

Hypercoordinated Oligosilanes Based on Aminotrisphenols
por: Aghazadeh Meshgi, Mohammad, et al.
Publicado: (2018)

σ-Aromaticity in planar pentacoordinate aluminium and gallium clusters
por: Kalita, Amlan J., et al.
Publicado: (2022)

σ-Aromatic MAl(6)S(6) (M = Ni, Pd, Pt) Stars Containing Planar Hexacoordinate Transition Metals
por: Bai, Li-Xia, et al.
Publicado: (2023)

As Nice as π: Aromatic Reactions Activated by π‐Coordination to Transition Metals
por: Williams, Luke J., et al.
Publicado: (2021)

Occurrence of Double Bond in π-Aromatic Rings: An Easy Way to Design Doubly Aromatic Carbon-Metal Structures
por: Tkachenko, Nikolay V., et al.
Publicado: (2021)

Aromatic Nanosandwich Obtained by σ-Dimerization of a Nanographenoid π-Radical
por: Moshniaha, Liliia, et al.
Publicado: (2020)

Reaction Mechanism of Li and Mg Carbenoid Cyclopropanations: Metal-π and σ Interactions
por: Villablanca, Daniel, et al.
Publicado: (2019)

Molecular recognition of planar and non-planar aromatic hydrocarbons through multipoint Ag–π bonding in a dinuclear metallo-macrocycle
por: Omoto, Kenichiro, et al.
Publicado: (2019)

Aminoboration: Addition of B–N σ Bonds across C–C π Bonds
por: Chong, Eugene, et al.
Publicado: (2015)

Analogy of the Reactions of Aromatic and Aliphatic π-Electrophiles with Nucleophiles
por: Barbasiewicz, Michał, et al.
Publicado: (2023)

A double bond with weak σ- and strong π-interactions is still a double bond
por: Foroutan-Nejad, Cina
Publicado: (2021)

Comparison between Tetrel Bonded Complexes Stabilized by σ and π Hole Interactions
por: Zierkiewicz, Wiktor, et al.
Publicado: (2018)

New Type of Halogen Bond: Multivalent Halogen Interacting with π- and σ-Electrons
por: Grabowski, Sławomir J.
Publicado: (2017)

Cooperation of σ–π and σ*–π* Conjugation in the UV/Vis and Fluorescence Spectra of 9,10-Disilylanthracene
por: Kyushin, Soichiro, et al.
Publicado: (2022)

Reply to: “A double bond with weak σ- and strong π-interactions is still a double bond”
por: Kyushin, Soichiro, et al.
Publicado: (2021)

Extension of the Simmons–Smith reaction to metal-carbynes: efficient synthesis of metallacyclopropenes with σ-aromaticity
por: Huang, Fanping, et al.
Publicado: (2020)

Metal-centered monocyclic carbon wheel clusters with record coordination numbers in planar species
por: Lu, Xiao-Qin, et al.
Publicado: (2021)

Characterization of the Effects of Ligands on Bonding and σ-Aromaticity of Small Pt Nanoclusters
por: Reid, Samantha, et al.
Publicado: (2023)

Multiyne chains chelating osmium via three metal-carbon σ bonds
por: Zhuo, Qingde, et al.
Publicado: (2017)

Chemical Bonding in Transition Metal Nitride Os(3)N(3)(+) Cluster: 6π Inorganic Benzene and δ(2)δ*(1)δ*(1) Aromaticity
por: Liu, Na, et al.
Publicado: (2018)

Analogies between Vanadoborates and Planar Aromatic Hydrocarbons: A High-Spin Analogue of Aromaticity
por: King, R. Bruce
Publicado: (2017)

Planar Cyclopenten‐4‐yl Cations: Highly Delocalized π Aromatics Stabilized by Hyperconjugation
por: Nees, Samuel, et al.
Publicado: (2020)

A Planar Five‐Membered Aromatic Ring Stabilized by Only Two π‐Electrons
por: Kysliak, Oleksandr, et al.
Publicado: (2022)

Theoretical Design of Novel Boron-Based Nanowires via Inverse Sandwich Clusters
por: Jiang, Cailian, et al.
Publicado: (2021)

Bonding in a Crystalline Tri‐Thorium Cluster: Not σ‐Aromatic But Still Unique
por: Szczepanik, Dariusz W.
Publicado: (2022)

Bonding Situation of σ‐E−H Complexes in Transition Metal and Main Group Compounds
por: Ríos, Pablo, et al.
Publicado: (2022)

Reversible carbon–boron bond formation at platinum centers through σ-BH complexes
por: Ríos, Pablo, et al.
Publicado: (2020)

Synthesis and Characterization of Hypercoordinated Silicon Anions: Catching Intermediates of Lewis Base Catalysis
por: Ansmann, Nils, et al.
Publicado: (2022)

Triel Bonds, π-Hole-π-Electrons Interactions in Complexes of Boron and Aluminium Trihalides and Trihydrides with Acetylene and Ethylene
por: Grabowski, Sławomir J.
Publicado: (2015)

Nb(2)©Au(6): a molecular wheel with a short Nb[triple bond, length as m-dash]Nb triple bond coordinated by an Au(6) ring and reinforced by σ aromaticity
por: Jian, Tian, et al.
Publicado: (2017)

Effect of the Granularity of Cubic Boron Nitride Vitrified Grinding Wheels on the Planar Technical Blades Sharpening Process
por: Zieliński, Bartosz, et al.
Publicado: (2022)

From π‐Bonded Gallapnictenes to Nucleophilic, Redox‐Active Metal‐Coordinated Pnictanides
por: Krüger, Julia, et al.
Publicado: (2020)

Capture of Fullerenes in Cages and Rings by Forming Metal-π Bond Arene Interactions
por: Rios, Citlalli, et al.
Publicado: (2021)

On the Bonding Nature in the Crystalline Tri‐Thorium Cluster: Core‐Shell Syngenetic σ‐Aromaticity
por: Lin, Xuhui, et al.
Publicado: (2022)

Hypercoordinate iodine for catalytic asymmetric diamination of styrene: insights into the mechanism, role of solvent, and stereoinduction
por: Sreenithya, A., et al.
Publicado: (2019)

Electrooxidation of Hypercoordinated Derivatives of Silicon and Reactivity of Their Electrogenerated Cation Radicals: 1-Substituted Silatranes
por: Romanovs, Vitalijs, et al.
Publicado: (2023)

Nitropyridine-1-Oxides as Excellent π-Hole Donors: Interplay between σ-Hole (Halogen, Hydrogen, Triel, and Coordination Bonds) and π-Hole Interactions
por: Galmés, Bartomeu, et al.
Publicado: (2019)

Cannot write session to /tmp/vufind_sessions/sess_nv1asriq2r9q08qoanlu6qmlan