Mechanisms of Sulfoxidation and Epoxidation Mediated by Iron(III)-Iodosylbenzene Adduct: Electron-Transfer vs. Oxygen-Transfer Mechanism

The mechanisms of sulfoxidation and epoxidation mediated by previously synthesized and characterized iron(III)-iodosylbenzene adduct, Fe(III)(OIPh) were investigated using para-substituted thioanisole and styrene derivatives as model substrates. Based on detailed kinetic reaction experiments, includ...

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Detalles Bibliográficos
Autores principales: Török, Patrik, Lakk-Bogáth, Dóra, Kaizer, József
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10305164/
https://www.ncbi.nlm.nih.gov/pubmed/37375303
http://dx.doi.org/10.3390/molecules28124745

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10305164/
https://www.ncbi.nlm.nih.gov/pubmed/37375303
http://dx.doi.org/10.3390/molecules28124745

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