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Disulfide radical anion as a super-reductant in biology and photoredox chemistry

Disulfides are involved in a broad range of radical-based synthetic organic and biochemical transformations. In particular, the reduction of a disulfide to the corresponding radical anion, followed by S–S bond cleavage to yield a thiyl radical and a thiolate anion plays critical roles in radical-bas...

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Detalles Bibliográficos
Autores principales: Zhu, Qilei, Costentin, Cyrille, Stubbe, JoAnne, Nocera, Daniel G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10306091/
https://www.ncbi.nlm.nih.gov/pubmed/37389245
http://dx.doi.org/10.1039/d3sc01867a