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Oxygen transfer reactivity mediated by nickel perfluoroalkyl complexes using molecular oxygen as a terminal oxidant

Nickel perfluoroethyl and perfluoropropyl complexes supported by naphthyridine-type ligands show drastically different aerobic reactivity from their trifluoromethyl analogs resulting in facile oxygen transfer to perfluoroalkyl groups or oxygenation of external organic substrates (phosphines, sulfide...

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Detalles Bibliográficos
Autores principales: Deolka, Shubham, Govindarajan, R., Khaskin, Eugene, Vasylevskyi, Serhii, Bahri, Janet, Fayzullin, Robert R., Roy, Michael C., Khusnutdinova, Julia R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10306096/
https://www.ncbi.nlm.nih.gov/pubmed/37389265
http://dx.doi.org/10.1039/d3sc01861j