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Insights into Synergistic Effects of Counterion and Ligand on Diastereoselectivity Switch in Gold-Catalyzed Post-Ugi Ipso-Cyclization

[Image: see text] The concept of diastereoselectivity switch in gold catalysis is investigated, which primarily depends on the effects of ligand and counterion. The origins of gold-catalyzed post-Ugi ipso-cyclization for the diastereoselective synthesis of spirocyclic pyrrol-2-one-dienone have been...

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Detalles Bibliográficos
Autores principales: He, Jun, Zhang, Jie, Li, Yunhe, Han, Yan-bo, Li, Mengyang, Zhao, Xiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10308395/
https://www.ncbi.nlm.nih.gov/pubmed/37396265
http://dx.doi.org/10.1021/acsomega.3c01279