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Lattice oxygen-mediated electron tuning promotes electrochemical hydrogenation of acetonitrile on copper catalysts

Copper is well-known to be selective to primary amines via electrocatalytic nitriles hydrogenation. However, the correlation between the local fine structure and catalytic selectivity is still illusive. Herein, we find that residual lattice oxygen in oxide-derived Cu nanowires (OD-Cu NWs) plays vita...

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Detalles Bibliográficos
Autores principales: Wei, Cong, Fang, Yanyan, Liu, Bo, Tang, Chongyang, Dong, Bin, Yin, Xuanwei, Bian, Zenan, Wang, Zhandong, Liu, Jun, Qian, Yitai, Wang, Gongming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10310717/
https://www.ncbi.nlm.nih.gov/pubmed/37386000
http://dx.doi.org/10.1038/s41467-023-39558-3