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Stabilization of propene molybdenum and tungsten half–sandwich complexes by intramolecular coordination of a thioether function
This study reports the stabilizing effect of an intramolecularly coordinated thioether function in propene complexes of the general formula [{η(5):κS-C(5)H(4)(CH(2))(2)SR}M(CO)(2)(η(2)-C(2)H(3)Me)][BF(4)] (M = Mo, W; R = Et, Ph). They are formed by protonation of allyl analogues [{η(5)-C(5)H(4)(CH(2...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10311468/ https://www.ncbi.nlm.nih.gov/pubmed/37396830 http://dx.doi.org/10.1039/d3ra03383j |