Stability and C–H Bond Activation Reactions of Palladium(I) and Platinum(I) Metalloradicals: Carbon-to-Metal H-Atom Transfer and an Organometallic Radical Rebound Mechanism

[Image: see text] One-electron oxidation of palladium(0) and platinum(0) bis(phosphine) complexes enables isolation of a homologous series of linear d(9) metalloradicals of the form [M(PR(3))(2)](+) (M = Pd, Pt; R = tBu, Ad), which are stable in 1,2-difluorobenzene (DFB) solution for >1 day at ro...

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Detalles Bibliográficos
Autores principales: Krämer, Tobias, Gyton, Matthew R., Bustos, Itxaso, Sinclair, Matthew J. G., Tan, Sze-yin, Wedge, Christopher J., Macgregor, Stuart A., Chaplin, Adrian B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10311531/
https://www.ncbi.nlm.nih.gov/pubmed/37318758
http://dx.doi.org/10.1021/jacs.3c04167

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10311531/
https://www.ncbi.nlm.nih.gov/pubmed/37318758
http://dx.doi.org/10.1021/jacs.3c04167

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