Cargando…

Stability and C–H Bond Activation Reactions of Palladium(I) and Platinum(I) Metalloradicals: Carbon-to-Metal H-Atom Transfer and an Organometallic Radical Rebound Mechanism

[Image: see text] One-electron oxidation of palladium(0) and platinum(0) bis(phosphine) complexes enables isolation of a homologous series of linear d(9) metalloradicals of the form [M(PR(3))(2)](+) (M = Pd, Pt; R = tBu, Ad), which are stable in 1,2-difluorobenzene (DFB) solution for >1 day at ro...

Descripción completa

Detalles Bibliográficos
Autores principales:	Krämer, Tobias, Gyton, Matthew R., Bustos, Itxaso, Sinclair, Matthew J. G., Tan, Sze-yin, Wedge, Christopher J., Macgregor, Stuart A., Chaplin, Adrian B.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2023
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10311531/ https://www.ncbi.nlm.nih.gov/pubmed/37318758 http://dx.doi.org/10.1021/jacs.3c04167

Ejemplares similares

Oxidative Addition of a Mechanically Entrapped C(sp)–C(sp) Bond to a Rhodium(I) Pincer Complex
por: Leforestier, Baptiste, et al.
Publicado: (2020)

Rhodium(I) Pincer Complexes of Nitrous Oxide
por: Gyton, Matthew R., et al.
Publicado: (2019)

Enantioselective radical process for synthesis of chiral indolines by metalloradical alkylation of diverse C(sp(3))–H bonds
por: Wen, Xin, et al.
Publicado: (2018)

Direct fluorogenic detection of palladium and platinum organometallic complexes with proteins and nucleic acids in polyacrylamide gels
por: Pekarik, Vladimir, et al.
Publicado: (2020)

Organometallic Palladium Reagents for Cysteine Bioconjugation
por: Vinogradova, Ekaterina V., et al.
Publicado: (2015)

Metalloradical Reactivity of Ru(I) and Ru(0) Stabilized by an Indole‐Based Tripodal Tetraphosphine Ligand
por: van de Watering, Fenna F., et al.
Publicado: (2017)

Carborane Stabilized “19-Electron” Molybdenum Metalloradical
por: Jaiswal, Kuldeep, et al.
Publicado: (2021)

Opening up the Valence Shell: A T‐Shaped Iron(I) Metalloradical and Its Potential for Atom Abstraction
por: Ott, Jonas C., et al.
Publicado: (2020)

An iron(ii)-based metalloradical system for intramolecular amination of C(sp(2))–H and C(sp(3))–H bonds: synthetic applications and mechanistic studies
por: Das, Sandip Kumar, et al.
Publicado: (2022)

Metalloradical Cations and Dications Based on Divinyldiphosphene and Divinyldiarsene Ligands
por: Sharma, Mahendra K., et al.
Publicado: (2021)

Mechanistic Insights into Molecular Crystalline Organometallic Heterogeneous Catalysis through Parahydrogen-Based Nuclear Magnetic Resonance Studies
por: Gyton, Matthew R., et al.
Publicado: (2023)

Stereoselective radical C–H alkylation with acceptor/acceptor-substituted diazo reagents via Co(ii)-based metalloradical catalysis
por: Cui, Xin, et al.
Publicado: (2015)

Metalloradical activation of α-formyldiazoacetates for the catalytic asymmetric radical cyclopropanation of alkenes
por: Xu, Xue, et al.
Publicado: (2017)

Studies of Nature of Uncommon Bifurcated I–I···(I–M) Metal-Involving Noncovalent Interaction in Palladium(II) and Platinum(II) Isocyanide Cocrystals
por: Bulatova, Margarita, et al.
Publicado: (2021)

Nanocrystalline SnO(2) Functionalized with Ag(I) Organometallic Complexes as Materials for Low Temperature H(2)S Detection
por: Goncharov, Timofei, et al.
Publicado: (2021)

Single-Crystal to Single-Crystal Addition of H(2) to [Ir((i)Pr-PONOP)(propene)][BAr(F)(4)] and Comparison Between Solid-State and Solution Reactivity
por: Royle, Cameron G., et al.
Publicado: (2022)

Palladium-Catalyzed Direct C=H Functionalization of Benzoquinone**
por: Walker, Sarah E, et al.
Publicado: (2014)

Metalation of Tellurophene: Reactivity of 21,23-Ditelluraporphodimethene toward Palladium(II), Platinum(II), and Rhodium(I)
por: Vetter, Grzegorz, et al.
Publicado: (2023)

Intramolecular 1,5-C(sp(3))–H radical amination via Co(ii)-based metalloradical catalysis for five-membered cyclic sulfamides
por: Lu, Hongjian, et al.
Publicado: (2016)

One‐Electron Oxidation of [M(P(t)Bu(3))(2)] (M=Pd, Pt): Isolation of Monomeric [Pd(P(t)Bu(3))(2)](+) and Redox‐Promoted C−H Bond Cyclometalation
por: Troadec, Thibault, et al.
Publicado: (2016)

A shape changing tandem Rh(CNC) catalyst: preparation of bicyclo[4.2.0]octa-1,5,7-trienes from terminal aryl alkynes
por: Storey, Caroline M., et al.
Publicado: (2020)

Rhodium(III) and Iridium(III) Complexes of a NHC-Based Macrocycle: Persistent Weak Agostic Interactions and Reactions with Dihydrogen
por: Gyton, Matthew R., et al.
Publicado: (2018)

Catalysis with Palladium(I) Dimers
por: Fricke, Christoph, et al.
Publicado: (2020)

Organometallic gold(I) and gold(III) complexes for lung cancer treatment
por: Zhang, Juzheng, et al.
Publicado: (2022)

A convenient method for the generation of {Rh(PNP)}(+) and {Rh(PONOP)}(+) fragments: reversible formation of vinylidene derivatives
por: Gyton, Matthew R., et al.
Publicado: (2019)

Comparison of the iCare rebound tonometer and the Goldmann applanation tonometer
por: Gao, Feng, et al.
Publicado: (2017)

Preliminary studies on the toxicity and metabolism of palladium and platinum.
por: Moore, W, et al.
Publicado: (1975)

Operation of platinum-palladium catalysts with leaded gasoline.
por: Teague, D M, et al.
Publicado: (1975)

To rebound or not to rebound
por: Stahl, Bethany A, et al.
Publicado: (2017)

Organometallics
por: Bochmann, Manfred
Publicado: (1994)

Rhodium and Iridium Mediated C-H and O-H Bond Activation of Two Schiff Base Ligands: Synthesis, Characterization and Catalytic Properties of the Organometallic Complexes
por: Sengupta, Poulami, et al.
Publicado: (2021)

Synthesis and Structural Dynamics of Five-Coordinate Rh(III) and Ir(III) PNP and PONOP Pincer Complexes
por: Hood, Thomas M., et al.
Publicado: (2019)

Strategies for palladium-catalyzed non-directed and directed C-H bond functionalization
por: Kapdi, Anant R, et al.
Publicado: (2017)

Levels of platinum, palladium, and lead in populations of Southern California.
por: Johnson, D E, et al.
Publicado: (1975)

Platinum, palladium, and lead levels in populations of Southern California.
por: Goldsmith, J R
Publicado: (1976)

Green Synthesis, Characterization and Uses of Palladium/Platinum Nanoparticles
por: Siddiqi, Khwaja Salahuddin, et al.
Publicado: (2016)

Platinum and Palladium Complexes as Promising Sources for Antitumor Treatments
por: Czarnomysy, Robert, et al.
Publicado: (2021)

Atomistic insights into the nucleation and growth of platinum on palladium nanocrystals
por: Gao, Wenpei, et al.
Publicado: (2021)

Synthesis, Molecular Docking and Cytotoxic Activity Evaluation of Organometallic Thiolated Gold(I) Complexes
por: Faghih, Zeinab, et al.
Publicado: (2020)

Terminal Alkyne Coupling Reactions through a Ring: Mechanistic Insights and Regiochemical Switching
por: Storey, Caroline M., et al.
Publicado: (2018)

Cannot write session to /tmp/vufind_sessions/sess_q62f0qj6b22l6v6m6eajc93suq