Photoredox catalysis enabling decarboxylative radical cyclization of γ,γ-dimethylallyltryptophan (DMAT) derivatives: formal synthesis of 6,7-secoagroclavine

An unusual photoredox-catalyzed radical decarboxylative cyclization cascade reaction of γ,γ-dimethylallyltryptophan (DMAT) derivatives containing unactivated alkene moieties has been developed, providing green and efficient access to various six-, seven-, and eight-membered ring 3,4-fused tricyclic...

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Detalles Bibliográficos
Autores principales: Regni, Alessio, Bartoccini, Francesca, Piersanti, Giovanni
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2023
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10315889/
https://www.ncbi.nlm.nih.gov/pubmed/37404801
http://dx.doi.org/10.3762/bjoc.19.70

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10315889/
https://www.ncbi.nlm.nih.gov/pubmed/37404801
http://dx.doi.org/10.3762/bjoc.19.70

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