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Nickel-Catalyzed 1,1-Aminoborylation of Unactivated Terminal Alkenes

[Image: see text] Herein, we disclose a Ni-catalyzed 1,1-difunctionalization of unactivated terminal alkenes that enables the incorporation of two different heteroatom motifs across an olefin backbone, thus streamlining the access to α-aminoboronic acid derivatives from simple precursors. The method...

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Detalles Bibliográficos
Autores principales: Talavera, Laura, Freund, Robert R. A., Zhang, Huihui, Wakeling, Matthew, Jensen, Mara, Martin, Ruben
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10316398/
https://www.ncbi.nlm.nih.gov/pubmed/37404837
http://dx.doi.org/10.1021/acscatal.3c00888