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Entropy stabilized cubic Li(7)La(3)Zr(2)O(12) with reduced lithium diffusion activation energy: studied using solid-state NMR spectroscopy
Stabilizing cubic polymorph of Li(7)La(3)Zr(2)O(12) at low temperatures is challenging and currently limited to mono- or dual-ion doping with aliovalent ions. Herein, a high-entropy strategy at the Zr sites was deployed to stabilize the cubic phase and lower the lithium diffusion activation energy,...
Autores principales: | , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10318413/ https://www.ncbi.nlm.nih.gov/pubmed/37409041 http://dx.doi.org/10.1039/d3ra02206d |