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Entropy stabilized cubic Li(7)La(3)Zr(2)O(12) with reduced lithium diffusion activation energy: studied using solid-state NMR spectroscopy

Stabilizing cubic polymorph of Li(7)La(3)Zr(2)O(12) at low temperatures is challenging and currently limited to mono- or dual-ion doping with aliovalent ions. Herein, a high-entropy strategy at the Zr sites was deployed to stabilize the cubic phase and lower the lithium diffusion activation energy,...

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Detalles Bibliográficos
Autores principales: Fan, Juntian, Wang, Tao, Bridges, Craig A., Borisevich, Albina Y., Steren, Carlos A., Li, Pengzhen, Thapaliya, Bishnu P., Do-Thanh, Chi-Linh, Yang, Zhenzhen, Yuan, Yating, Dai, Sheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10318413/
https://www.ncbi.nlm.nih.gov/pubmed/37409041
http://dx.doi.org/10.1039/d3ra02206d