Entropy stabilized cubic Li(7)La(3)Zr(2)O(12) with reduced lithium diffusion activation energy: studied using solid-state NMR spectroscopy

Stabilizing cubic polymorph of Li(7)La(3)Zr(2)O(12) at low temperatures is challenging and currently limited to mono- or dual-ion doping with aliovalent ions. Herein, a high-entropy strategy at the Zr sites was deployed to stabilize the cubic phase and lower the lithium diffusion activation energy,...

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Autores principales: Fan, Juntian, Wang, Tao, Bridges, Craig A., Borisevich, Albina Y., Steren, Carlos A., Li, Pengzhen, Thapaliya, Bishnu P., Do-Thanh, Chi-Linh, Yang, Zhenzhen, Yuan, Yating, Dai, Sheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10318413/
https://www.ncbi.nlm.nih.gov/pubmed/37409041
http://dx.doi.org/10.1039/d3ra02206d
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author Fan, Juntian
Wang, Tao
Bridges, Craig A.
Borisevich, Albina Y.
Steren, Carlos A.
Li, Pengzhen
Thapaliya, Bishnu P.
Do-Thanh, Chi-Linh
Yang, Zhenzhen
Yuan, Yating
Dai, Sheng
author_facet Fan, Juntian
Wang, Tao
Bridges, Craig A.
Borisevich, Albina Y.
Steren, Carlos A.
Li, Pengzhen
Thapaliya, Bishnu P.
Do-Thanh, Chi-Linh
Yang, Zhenzhen
Yuan, Yating
Dai, Sheng
author_sort Fan, Juntian
collection PubMed
description Stabilizing cubic polymorph of Li(7)La(3)Zr(2)O(12) at low temperatures is challenging and currently limited to mono- or dual-ion doping with aliovalent ions. Herein, a high-entropy strategy at the Zr sites was deployed to stabilize the cubic phase and lower the lithium diffusion activation energy, evident from the static (7)Li and MAS (6)Li NMR spectra.
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spelling pubmed-103184132023-07-05 Entropy stabilized cubic Li(7)La(3)Zr(2)O(12) with reduced lithium diffusion activation energy: studied using solid-state NMR spectroscopy Fan, Juntian Wang, Tao Bridges, Craig A. Borisevich, Albina Y. Steren, Carlos A. Li, Pengzhen Thapaliya, Bishnu P. Do-Thanh, Chi-Linh Yang, Zhenzhen Yuan, Yating Dai, Sheng RSC Adv Chemistry Stabilizing cubic polymorph of Li(7)La(3)Zr(2)O(12) at low temperatures is challenging and currently limited to mono- or dual-ion doping with aliovalent ions. Herein, a high-entropy strategy at the Zr sites was deployed to stabilize the cubic phase and lower the lithium diffusion activation energy, evident from the static (7)Li and MAS (6)Li NMR spectra. The Royal Society of Chemistry 2023-07-04 /pmc/articles/PMC10318413/ /pubmed/37409041 http://dx.doi.org/10.1039/d3ra02206d Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Fan, Juntian
Wang, Tao
Bridges, Craig A.
Borisevich, Albina Y.
Steren, Carlos A.
Li, Pengzhen
Thapaliya, Bishnu P.
Do-Thanh, Chi-Linh
Yang, Zhenzhen
Yuan, Yating
Dai, Sheng
Entropy stabilized cubic Li(7)La(3)Zr(2)O(12) with reduced lithium diffusion activation energy: studied using solid-state NMR spectroscopy
title Entropy stabilized cubic Li(7)La(3)Zr(2)O(12) with reduced lithium diffusion activation energy: studied using solid-state NMR spectroscopy
title_full Entropy stabilized cubic Li(7)La(3)Zr(2)O(12) with reduced lithium diffusion activation energy: studied using solid-state NMR spectroscopy
title_fullStr Entropy stabilized cubic Li(7)La(3)Zr(2)O(12) with reduced lithium diffusion activation energy: studied using solid-state NMR spectroscopy
title_full_unstemmed Entropy stabilized cubic Li(7)La(3)Zr(2)O(12) with reduced lithium diffusion activation energy: studied using solid-state NMR spectroscopy
title_short Entropy stabilized cubic Li(7)La(3)Zr(2)O(12) with reduced lithium diffusion activation energy: studied using solid-state NMR spectroscopy
title_sort entropy stabilized cubic li(7)la(3)zr(2)o(12) with reduced lithium diffusion activation energy: studied using solid-state nmr spectroscopy
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10318413/
https://www.ncbi.nlm.nih.gov/pubmed/37409041
http://dx.doi.org/10.1039/d3ra02206d
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