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Enhanced enantioselectivity in halogen-bonding catalysis

Chiral halogen-bonding catalysts have emerged as a new approach towards asymmetric catalysis, but enantioselectivities have thus far remained low. Now, fine-tuning the substrate–catalyst halogen–halogen interactions is shown to significantly enhance enantioselectivity for a model anion-binding-catal...

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Detalles Bibliográficos
Autor principal: Richards, Victoria
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10319721/
https://www.ncbi.nlm.nih.gov/pubmed/37402818
http://dx.doi.org/10.1038/s42004-023-00940-3