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Enhanced enantioselectivity in halogen-bonding catalysis
Chiral halogen-bonding catalysts have emerged as a new approach towards asymmetric catalysis, but enantioselectivities have thus far remained low. Now, fine-tuning the substrate–catalyst halogen–halogen interactions is shown to significantly enhance enantioselectivity for a model anion-binding-catal...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Nature Publishing Group UK
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10319721/ https://www.ncbi.nlm.nih.gov/pubmed/37402818 http://dx.doi.org/10.1038/s42004-023-00940-3 |