Bidirectional photoswitchability in an iron(iii) spin crossover complex: symmetry-breaking and solvent effects

The impact of solvent on spin crossover (SCO) behaviour is reported in two solvates [Fe(qsal-I)(2)]NO(3)·2ROH (qsal-I = 4-iodo-2-[(8-quinolylimino)methyl]phenolate; R = Me 1 or Et 2) which undergo abrupt and gradual SCO, respectively. A symmetry-breaking phase transition due to spin-state ordering f...

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Detalles Bibliográficos
Autores principales: Díaz-Torres, Raúl, Chastanet, Guillaume, Collet, Eric, Trzop, Elzbieta, Harding, Phimphaka, Harding, David J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10321481/
https://www.ncbi.nlm.nih.gov/pubmed/37416698
http://dx.doi.org/10.1039/d3sc01495a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10321481/
https://www.ncbi.nlm.nih.gov/pubmed/37416698
http://dx.doi.org/10.1039/d3sc01495a

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