Cargando…

Bidirectional photoswitchability in an iron(iii) spin crossover complex: symmetry-breaking and solvent effects

The impact of solvent on spin crossover (SCO) behaviour is reported in two solvates [Fe(qsal-I)(2)]NO(3)·2ROH (qsal-I = 4-iodo-2-[(8-quinolylimino)methyl]phenolate; R = Me 1 or Et 2) which undergo abrupt and gradual SCO, respectively. A symmetry-breaking phase transition due to spin-state ordering f...

Descripción completa

Detalles Bibliográficos
Autores principales:	Díaz-Torres, Raúl, Chastanet, Guillaume, Collet, Eric, Trzop, Elzbieta, Harding, Phimphaka, Harding, David J.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2023
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10321481/ https://www.ncbi.nlm.nih.gov/pubmed/37416698 http://dx.doi.org/10.1039/d3sc01495a

Ejemplares similares

Solvent modified spin crossover in an iron(iii) complex: phase changes and an exceptionally wide hysteresis
por: Phonsri, Wasinee, et al.
Publicado: (2017)

Room temperature conductance switching in a molecular iron(iii) spin crossover junction
por: Karuppannan, Senthil Kumar, et al.
Publicado: (2020)

Crossovers break SC symmetry
por: LeBrasseur, Nicole
Publicado: (2005)

Increasing spin crossover cooperativity in 2D Hofmann-type materials with guest molecule removal
por: Zenere, Katrina A., et al.
Publicado: (2018)

Solvent-Induced Polymorphism of Iron(II) Spin Crossover Complexes
por: Šalitroš, Ivan, et al.
Publicado: (2016)

Mapping the cooperativity pathways in spin crossover complexes
por: Reeves, Matthew G., et al.
Publicado: (2020)

Spray-Drying to Get Spin-Crossover Materials
por: Daro, Nathalie, et al.
Publicado: (2017)

Domain Wall Dynamics in a Ferroelastic Spin Crossover Complex with Giant Magnetoelectric Coupling
por: Jakobsen, Vibe Boel, et al.
Publicado: (2021)

Stress‐Induced Domain Wall Motion in a Ferroelastic Mn(3+) Spin Crossover Complex
por: Jakobsen, Vibe B., et al.
Publicado: (2020)

Breaking the photoswitch speed limit
por: Thaggard, Grace C., et al.
Publicado: (2023)

Replica symmetry breaking effects in spin glasses
por: Ritort, F
Publicado: (1994)

Guest induced reversible on–off switching of elastic frustration in a 3D spin crossover coordination polymer with room temperature hysteretic behaviour
por: Piñeiro-López, Lucía, et al.
Publicado: (2020)

Multiscale Experimental and Theoretical Investigations of Spin Crossover Fe(II) Complexes: Examples of [Fe(phen)(2)(NCS)(2)] and [Fe(PM-BiA)(2)(NCS)(2)]
por: Matar, Samir F., et al.
Publicado: (2015)

Tris(phenanthroline-κ(2) N,N′)cobalt(II) tetrafluoridoborate acetonitrile solvate
por: Harding, David J., et al.
Publicado: (2008)

(8-Aminoquinoline-κ(2) N,N′)bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato-κ(2) O,O′)cobalt(II)
por: Harding, David J., et al.
Publicado: (2012)

[Tris(3,5-diphenylpyrazolyl)hydroborato]nickel(II) bromide
por: Harding, David J., et al.
Publicado: (2009)

(Di-2-pyridylamine-κ(2) N,N′)[hydrotris(3,5-diphenylpyrazol-1-yl-κN (2))borato]nickel(II) bromide dichloromethane monosolvate
por: Harding, David J., et al.
Publicado: (2011)

Solvent tuning of photochemistry upon excited-state symmetry breaking
por: Dereka, Bogdan, et al.
Publicado: (2020)

Spin crossover-induced colossal positive and negative thermal expansion in a nanoporous coordination framework material
por: Mullaney, Benjamin R., et al.
Publicado: (2017)

Tris(5-methyl-3-phenyl-1H-pyrazol-1-yl)methane
por: Harding, David J., et al.
Publicado: (2008)

Spin revolution breaks time reversal symmetry of rolling magnets
por: Vedmedenko, Elena Y., et al.
Publicado: (2022)

Breaking the Symmetry of Pyrimidine: Solvent Effects and Core-Excited State Dynamics
por: Eckert, Sebastian, et al.
Publicado: (2021)

[4-Bromo-N-(pyridin-2-ylmethylidene)aniline-κ(2) N,N′]bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato-κ(2) O,O′)nickel(II)
por: Harding, Phimphaka, et al.
Publicado: (2011)

[(4-Bromophenyl)(2-pyridylmethylidene)amine-κ(2) N,N′]bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato-κ(2) O,O′)cobalt(II)
por: Harding, Phimphaka, et al.
Publicado: (2010)

Iron(II) Spin Crossover Complexes with 4,4′-Dipyridylethyne—Crystal Structures and Spin Crossover with Hysteresis
por: Dankhoff, Katja, et al.
Publicado: (2020)

Spin-State Patterning in an Iron(II) Tripodal Spin-Crossover Complex
por: Li, Li, et al.
Publicado: (2017)

The spin density functions of the nucleon, flavour symmetry breaking, and chiral dynamics
por: Fritzsch, Harald
Publicado: (1990)

Order–Disorder, Symmetry Breaking, and Crystallographic Phase Transition in a Series of Bis(trans-thiocyanate)iron(II) Spin Crossover Complexes Based on Tetradentate Ligands Containing 1,2,3-Triazoles
por: Seredyuk, Maksym, et al.
Publicado: (2023)

Symmetry breaking /
por: Strocchi, F.
Publicado: (2005)

Symmetry Breaking
por: Strocchi, Franco
Publicado: (2005)

Symmetry Breaking
por: Strocchi, Franco
Publicado: (2007)

Symmetry breaking
por: Strocchi, Franco
Publicado: (2021)

Optical spin-symmetry breaking for high-efficiency directional helicity-multiplexed metaholograms
por: Naveed, Muhammad Ashar, et al.
Publicado: (2021)

Toward Simulation of Fe(II) Low-Spin → High-Spin Photoswitching by Synergistic Spin-Vibronic Dynamics
por: Pápai, Mátyás
Publicado: (2022)

Synthesis and Characterization of a Bidirectional Photoswitchable Antagonist Toolbox for Real-Time GPCR Photopharmacology
por: Hauwert, Niels J., et al.
Publicado: (2018)

Solvent Effects on the Actinic Step of Donor–Acceptor Stenhouse Adduct Photoswitching
por: Lerch, Michael M., et al.
Publicado: (2018)

Breaking photoswitch activation depth limit using ionising radiation stimuli adapted to clinical application
por: Guesdon-Vennerie, Alban, et al.
Publicado: (2022)

Periodontitis and Dementia: A Bidirectional Relationship?
por: Harding, A., et al.
Publicado: (2021)

Symmetries and symmetry breaking in field theory
por: Mitra, P
Publicado: (2014)

Symmetry breaking at enhanced symmetry points
por: Green, Michael B., et al.
Publicado: (1995)

Cannot write session to /tmp/vufind_sessions/sess_d5jtp12p9im58umdjaqupo5b0k