Catalytic asymmetric defluorinative allylation of silyl enol ethers

The stereocontrolled installation of alkyl fragments at the alpha position of ketones is a fundamental yet unresolved transformation in organic chemistry. Herein we report a new catalytic methodology able to construct α-allyl ketones via defluorinative allylation of silyl enol ethers in a regio-, di...

Descripción completa

Detalles Bibliográficos
Autores principales: Duran, Jordi, Mateos, Javier, Moyano, Albert, Companyó, Xavier
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10321495/
https://www.ncbi.nlm.nih.gov/pubmed/37416711
http://dx.doi.org/10.1039/d3sc01498c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10321495/
https://www.ncbi.nlm.nih.gov/pubmed/37416711
http://dx.doi.org/10.1039/d3sc01498c

Ejemplares similares