Controlled introduction of functional groups at one P atom in [Cp*Fe(η(5)-P(5))] and release of functionalised phosphines

By salt metathesis reactions of the anionic complexes of the type [Cp*Fe(η(4)-P(5)R)](−) (R = (t)Bu (1a), Me (1b), –C[triple bond, length as m-dash]CPh (1c); Cp* = 1,2,3,4,5-pentamethylcyclopentadienyl) with organic electrophiles (XR(FG); X = halogen; R(FG) = (CH(2))(3)Br, (CH(2))(4)Br, Me) a variet...

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Detalles Bibliográficos
Autores principales: Reichl, Stephan, Riedlberger, Felix, Piesch, Martin, Balázs, Gábor, Seidl, Michael, Scheer, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10321501/
https://www.ncbi.nlm.nih.gov/pubmed/37416701
http://dx.doi.org/10.1039/d3sc01488f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10321501/
https://www.ncbi.nlm.nih.gov/pubmed/37416701
http://dx.doi.org/10.1039/d3sc01488f

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