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Controlled introduction of functional groups at one P atom in [Cp*Fe(η(5)-P(5))] and release of functionalised phosphines
By salt metathesis reactions of the anionic complexes of the type [Cp*Fe(η(4)-P(5)R)](−) (R = (t)Bu (1a), Me (1b), –C[triple bond, length as m-dash]CPh (1c); Cp* = 1,2,3,4,5-pentamethylcyclopentadienyl) with organic electrophiles (XR(FG); X = halogen; R(FG) = (CH(2))(3)Br, (CH(2))(4)Br, Me) a variet...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10321501/ https://www.ncbi.nlm.nih.gov/pubmed/37416701 http://dx.doi.org/10.1039/d3sc01488f |