Defying the inverse energy gap law: a vacuum-evaporable Fe(ii) low-spin complex with a long-lived LIESST state

The novel vacuum-evaporable complex [Fe(pypypyr)(2)] (pypypyr = bipyridyl pyrrolide) was synthesised and analysed as bulk material and as a thin film. In both cases, the compound is in its low-spin state up to temperatures of at least 510 K. Thus, it is conventionally considered a pure low-spin comp...

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Detalles Bibliográficos
Autores principales: Grunwald, Jan, Torres, Jorge, Buchholz, Axel, Näther, Christian, Kämmerer, Lea, Gruber, Manuel, Rohlf, Sebastian, Thakur, Sangeeta, Wende, Heiko, Plass, Winfried, Kuch, Wolfgang, Tuczek, Felix
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10321519/
https://www.ncbi.nlm.nih.gov/pubmed/37416721
http://dx.doi.org/10.1039/d3sc00561e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10321519/
https://www.ncbi.nlm.nih.gov/pubmed/37416721
http://dx.doi.org/10.1039/d3sc00561e

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