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Mn(II), Fe(II), and Co(II) Aryloxides: Steric and Dispersion Effects and the Thermal Rearrangement of a Cobalt Aryloxide to a Co(II) Semiquinone Complex

[Image: see text] A series of Mn(II), Fe(II), and Co(II) bisaryloxide dimers ([M(OC(6)H(2)-2,4,6-Cy(3))(2)](2) {M = Mn (1), Fe (2), and Co (3)} were synthesized by the addition of 2,4,6-tricyclohexylphenol (HOC(6)H(2)-2,4,6-Cy(3)) to the silyl amido dimers [M(N(SiMe(3))(2))(2)](2) (M = Mn, Fe, Co; C...

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Detalles Bibliográficos
Autores principales: McLoughlin, Connor P., Fettinger, James C., Power, Philip P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10324311/
https://www.ncbi.nlm.nih.gov/pubmed/37343531
http://dx.doi.org/10.1021/acs.inorgchem.3c00610