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Mn(II), Fe(II), and Co(II) Aryloxides: Steric and Dispersion Effects and the Thermal Rearrangement of a Cobalt Aryloxide to a Co(II) Semiquinone Complex
[Image: see text] A series of Mn(II), Fe(II), and Co(II) bisaryloxide dimers ([M(OC(6)H(2)-2,4,6-Cy(3))(2)](2) {M = Mn (1), Fe (2), and Co (3)} were synthesized by the addition of 2,4,6-tricyclohexylphenol (HOC(6)H(2)-2,4,6-Cy(3)) to the silyl amido dimers [M(N(SiMe(3))(2))(2)](2) (M = Mn, Fe, Co; C...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10324311/ https://www.ncbi.nlm.nih.gov/pubmed/37343531 http://dx.doi.org/10.1021/acs.inorgchem.3c00610 |