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A Remarkably Unsymmetric Hexairon Core Embraced by Two High-Symmetry Tripodal Oligo-α-pyridylamido Ligands

[Image: see text] Oligo-α-pyridylamides offer an appealing route to polyiron complexes with short Fe–Fe separations and large room-temperature magnetic moments. A derivative of tris(2-aminoethyl)amine (H(6)tren) containing three oligo-α-pyridylamine branches and 13 nitrogen donors (H(6)L) reacts wit...

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Detalles Bibliográficos
Autores principales: Nicolini, Alessio, Pankratz, Trey C., Borsari, Marco, Clérac, Rodolphe, Ranieri, Antonio, Rouzières, Mathieu, Berry, John F., Cornia, Andrea
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10324315/
https://www.ncbi.nlm.nih.gov/pubmed/37345231
http://dx.doi.org/10.1021/acs.inorgchem.3c00808