[3 + 2] Cycloadditions of Tertiary Amine N-Oxides and Silyl Imines as an Innovative Route to 1,2-Diamines

[Image: see text] We have developed a one-pot synthetic method for producing 1,2-diamines from easily prepared and commercially available precursors through a formal umpolung process. Our method utilizes an efficient [3 + 2] cycloaddition as the key step in forming substituted 1,2-diamines in modera...

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Detalles Bibliográficos
Autores principales: Hejnosz, Sarah L., Beres, Danielle R., Cocolas, Alexander H., Neal, Martin J., Musiak, Benjamin S., Hanna, Marianne M. B., Bloomfield, Aaron J., Montgomery, Thomas D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10325142/
https://www.ncbi.nlm.nih.gov/pubmed/37318514
http://dx.doi.org/10.1021/acs.orglett.3c01396

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10325142/
https://www.ncbi.nlm.nih.gov/pubmed/37318514
http://dx.doi.org/10.1021/acs.orglett.3c01396

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