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Stabilizing Effect of a 4c/6e Hypervalent Bond in Dinitrodiphenyl Disulfides and Their Thermochemical Properties: Experimental and Computational Approach

[Image: see text] Thermochemical properties and intramolecular interactions of 2,2′-dinitrodiphenyl disulfide (2DNDPDS) and 4,4′-dinitrodiphenyl disulfide (4DNDPDS) were determined and analyzed. Their standard molar formation enthalpies in the gas phase (Δ(f)H(m)(°)(g)’s) were experimentally determi...

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Detalles Bibliográficos
Autores principales: Flores, Henoc, Ramos, Fernando, Hernández-Pérez, Julio M., Solano-Altamirano, Juan M., Camarillo, E. Adriana, Sandoval-Lira, Jacinto
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10331731/
https://www.ncbi.nlm.nih.gov/pubmed/37365903
http://dx.doi.org/10.1021/acs.jpca.3c01624