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Stabilizing Effect of a 4c/6e Hypervalent Bond in Dinitrodiphenyl Disulfides and Their Thermochemical Properties: Experimental and Computational Approach
[Image: see text] Thermochemical properties and intramolecular interactions of 2,2′-dinitrodiphenyl disulfide (2DNDPDS) and 4,4′-dinitrodiphenyl disulfide (4DNDPDS) were determined and analyzed. Their standard molar formation enthalpies in the gas phase (Δ(f)H(m)(°)(g)’s) were experimentally determi...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10331731/ https://www.ncbi.nlm.nih.gov/pubmed/37365903 http://dx.doi.org/10.1021/acs.jpca.3c01624 |