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Polythioethers bearing side groups for efficient degradation by E1cB reaction: reaction design for polymerization and main-chain scission

We have previously reported the polycondensation by the tandem reactions of dithiols and α-(bromomethyl)acrylates, consisting of conjugate substitution (S(N)2′ reaction) and conjugate addition (Michael addition) reactions. The resulting polythioethers underwent a main-chain scission (MCS) by E1cB re...

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Detalles Bibliográficos
Autores principales: Kawatani, Ryo, Hagiwara, Keito, Tanaka, Anri, Kohsaka, Yasuhiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10332248/
https://www.ncbi.nlm.nih.gov/pubmed/37435381
http://dx.doi.org/10.1039/d3ra03751g