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Polythioethers bearing side groups for efficient degradation by E1cB reaction: reaction design for polymerization and main-chain scission
We have previously reported the polycondensation by the tandem reactions of dithiols and α-(bromomethyl)acrylates, consisting of conjugate substitution (S(N)2′ reaction) and conjugate addition (Michael addition) reactions. The resulting polythioethers underwent a main-chain scission (MCS) by E1cB re...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10332248/ https://www.ncbi.nlm.nih.gov/pubmed/37435381 http://dx.doi.org/10.1039/d3ra03751g |