Binding Small Molecules to a cis-Dicarbonyl (99)Tc(I)-PNP Complex via Metal–Ligand Cooperativity

[Image: see text] Metal–ligand cooperativity is a powerful tool for the activation of various bonds but has rarely, if ever, been studied with the radioactive transition metal (99)Tc. In this work, we explore this bond activation pathway with the dearomatized PNP complex cis-[(99)Tc(I)((Pyr)PNP(tBu)...

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Detalles Bibliográficos
Autores principales: Besmer, Manuel Luca, Braband, Henrik, Fox, Thomas, Spingler, Bernhard, Sattelberger, Alfred P., Alberto, Roger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10336964/
https://www.ncbi.nlm.nih.gov/pubmed/37351561
http://dx.doi.org/10.1021/acs.inorgchem.3c01177

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10336964/
https://www.ncbi.nlm.nih.gov/pubmed/37351561
http://dx.doi.org/10.1021/acs.inorgchem.3c01177

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