A Cavity-Shaped Gold(I) Fragment Enables CO(2) Insertion into Au–OH and Au–NH Bonds

[Image: see text] A cavity-shaped linear gold(I) hydroxide complex acts as a platform to access unusual gold monomeric species. Notably, this sterically crowded gold fragment enables the trapping of CO(2) via insertion into Au–OH and Au–NH bonds to form unprecedented monomeric gold(I) carbonate and...

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Detalles Bibliográficos
Autores principales: Navarro, Miquel, Holzapfel, Markus, Campos, Jesús
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10336967/
https://www.ncbi.nlm.nih.gov/pubmed/37367828
http://dx.doi.org/10.1021/acs.inorgchem.3c00751

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10336967/
https://www.ncbi.nlm.nih.gov/pubmed/37367828
http://dx.doi.org/10.1021/acs.inorgchem.3c00751

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