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A Cavity-Shaped Gold(I) Fragment Enables CO(2) Insertion into Au–OH and Au–NH Bonds
[Image: see text] A cavity-shaped linear gold(I) hydroxide complex acts as a platform to access unusual gold monomeric species. Notably, this sterically crowded gold fragment enables the trapping of CO(2) via insertion into Au–OH and Au–NH bonds to form unprecedented monomeric gold(I) carbonate and...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10336967/ https://www.ncbi.nlm.nih.gov/pubmed/37367828 http://dx.doi.org/10.1021/acs.inorgchem.3c00751 |