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Difluoromethylborates and Muonium for the Study of Isonitrile Insertion Affording Phenanthridines via Imidoyl Radicals

[Image: see text] The 6-(difluoromethyl)phenanthridine unit is a highly attractive fluoroalkyl-substituted planar nitrogen heterocycle in pharmaceutical and agrochemical research. In this paper, we report that difluoromethylborates can be used as a source of difluoromethyl radicals for isonitrile in...

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Detalles Bibliográficos
Autores principales: Konagaya, Kakeru, Huang, Yu-En, Iwami, Kazuki, Fujino, Tetsuya, Abe, Rikutaro, Parchment-Morrison, Reuben, Kojima, Kenji M., McKenzie, Iain, Ito, Shigekazu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10337039/
https://www.ncbi.nlm.nih.gov/pubmed/37351949
http://dx.doi.org/10.1021/acs.joc.3c00056