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Synthesis, Structure, and Spectroscopy of the Biscarboranyl Stannylenes (bc)Sn·THF and K(2)[(bc)Sn](2) (bc = 1,1′(ortho-Biscarborane)) and Dibiscarboranyl Ethene (bc)CH=CH(bc)
[Image: see text] Two compounds containing a Sn(II) atom supported by a bidentate biscarborane ligand have been synthesized via salt metathesis. The synthetic procedures for (bc)Sn·THF (bc = 1,1′ (ortho-carborane) (1) and K(2)[(bc)Sn](2) (2) involved the reaction of K(2)[bc] with SnCl(2) in either a...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10337257/ https://www.ncbi.nlm.nih.gov/pubmed/37448537 http://dx.doi.org/10.1021/acs.organomet.3c00190 |