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(CAAC)Pd(py) Catalysts Disproportionate to Pd(CAAC)(2)
[Image: see text] Palladium complexes with one N-heterocyclic carbene (NHC) and a pyridine ancillary ligand are powerful cross-coupling precatalysts. Herein, we report such complexes with a cyclic (alkyl)(amino)carbene (CAAC) ligand replacing the NHC. We find that the alleged reduced form, (CAAC)Pd(...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10337258/ https://www.ncbi.nlm.nih.gov/pubmed/37448536 http://dx.doi.org/10.1021/acs.organomet.3c00150 |