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(CAAC)Pd(py) Catalysts Disproportionate to Pd(CAAC)(2)

[Image: see text] Palladium complexes with one N-heterocyclic carbene (NHC) and a pyridine ancillary ligand are powerful cross-coupling precatalysts. Herein, we report such complexes with a cyclic (alkyl)(amino)carbene (CAAC) ligand replacing the NHC. We find that the alleged reduced form, (CAAC)Pd(...

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Detalles Bibliográficos
Autores principales:	Marigo, Nicola, Morgenstern, Bernd, Biffis, Andrea, Munz, Dominik
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2023
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10337258/ https://www.ncbi.nlm.nih.gov/pubmed/37448536 http://dx.doi.org/10.1021/acs.organomet.3c00150

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