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Amorphous/Nanocrystalline High-Entropy CoCrFeNiTi(x) Thin Films with Low Thermal Coefficient of Resistivity Obtained via Magnetron Deposition
High-entropy alloys are promising materials for novel thin-film resistors since they have high resistivity and a low-temperature coefficient of resistivity (TCR). In this work, a new high-entropy thin-film CoCrFeNiTi(x) was deposited on a Si/SiO(2) substrate by means of magnetron sputtering of the m...
Autores principales: | , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10343313/ https://www.ncbi.nlm.nih.gov/pubmed/37446519 http://dx.doi.org/10.3390/nano13132004 |
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author | Poliakov, Maksim Kovalev, Dmitry Vadchenko, Sergei Moskovskikh, Dmitry Kiryukhantsev-Korneev, Philipp Volkova, Lidiya Dudin, Alexander Orlov, Andrey Goryachev, Andrey Rogachev, Alexander |
author_facet | Poliakov, Maksim Kovalev, Dmitry Vadchenko, Sergei Moskovskikh, Dmitry Kiryukhantsev-Korneev, Philipp Volkova, Lidiya Dudin, Alexander Orlov, Andrey Goryachev, Andrey Rogachev, Alexander |
author_sort | Poliakov, Maksim |
collection | PubMed |
description | High-entropy alloys are promising materials for novel thin-film resistors since they have high resistivity and a low-temperature coefficient of resistivity (TCR). In this work, a new high-entropy thin-film CoCrFeNiTi(x) was deposited on a Si/SiO(2) substrate by means of magnetron sputtering of the multi-component target produced by hot pressing of the powder mixture. The samples possessed a thickness of 130–230 nm and an amorphous atomic structure with nanocrystallite traces. This structure persisted after being annealed up to 400 °C, which was confirmed using X-ray and electron diffraction. The film had a single-phase structure with a smooth surface and a uniform distribution of all elements. The obtained film served for microresistor elaboration, which was produced using the lithography technique and tested in a temperature range from −60 °C up to 200 °C. Resistivity at room temperature was estimated as 2.37 μOhm·m. The results have demonstrated that TCR depends on temperature according to the simple linear law in a range from −60 °C up to 130 °C, changing its value from −78 ppm/°C at low temperatures to −6.6 ppm/°C at 130 °C. Such characteristics show the possibility of using these high-entropy alloy films for resistive elements in contemporary and future micro-electronic devices. |
format | Online Article Text |
id | pubmed-10343313 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-103433132023-07-14 Amorphous/Nanocrystalline High-Entropy CoCrFeNiTi(x) Thin Films with Low Thermal Coefficient of Resistivity Obtained via Magnetron Deposition Poliakov, Maksim Kovalev, Dmitry Vadchenko, Sergei Moskovskikh, Dmitry Kiryukhantsev-Korneev, Philipp Volkova, Lidiya Dudin, Alexander Orlov, Andrey Goryachev, Andrey Rogachev, Alexander Nanomaterials (Basel) Article High-entropy alloys are promising materials for novel thin-film resistors since they have high resistivity and a low-temperature coefficient of resistivity (TCR). In this work, a new high-entropy thin-film CoCrFeNiTi(x) was deposited on a Si/SiO(2) substrate by means of magnetron sputtering of the multi-component target produced by hot pressing of the powder mixture. The samples possessed a thickness of 130–230 nm and an amorphous atomic structure with nanocrystallite traces. This structure persisted after being annealed up to 400 °C, which was confirmed using X-ray and electron diffraction. The film had a single-phase structure with a smooth surface and a uniform distribution of all elements. The obtained film served for microresistor elaboration, which was produced using the lithography technique and tested in a temperature range from −60 °C up to 200 °C. Resistivity at room temperature was estimated as 2.37 μOhm·m. The results have demonstrated that TCR depends on temperature according to the simple linear law in a range from −60 °C up to 130 °C, changing its value from −78 ppm/°C at low temperatures to −6.6 ppm/°C at 130 °C. Such characteristics show the possibility of using these high-entropy alloy films for resistive elements in contemporary and future micro-electronic devices. MDPI 2023-07-04 /pmc/articles/PMC10343313/ /pubmed/37446519 http://dx.doi.org/10.3390/nano13132004 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Poliakov, Maksim Kovalev, Dmitry Vadchenko, Sergei Moskovskikh, Dmitry Kiryukhantsev-Korneev, Philipp Volkova, Lidiya Dudin, Alexander Orlov, Andrey Goryachev, Andrey Rogachev, Alexander Amorphous/Nanocrystalline High-Entropy CoCrFeNiTi(x) Thin Films with Low Thermal Coefficient of Resistivity Obtained via Magnetron Deposition |
title | Amorphous/Nanocrystalline High-Entropy CoCrFeNiTi(x) Thin Films with Low Thermal Coefficient of Resistivity Obtained via Magnetron Deposition |
title_full | Amorphous/Nanocrystalline High-Entropy CoCrFeNiTi(x) Thin Films with Low Thermal Coefficient of Resistivity Obtained via Magnetron Deposition |
title_fullStr | Amorphous/Nanocrystalline High-Entropy CoCrFeNiTi(x) Thin Films with Low Thermal Coefficient of Resistivity Obtained via Magnetron Deposition |
title_full_unstemmed | Amorphous/Nanocrystalline High-Entropy CoCrFeNiTi(x) Thin Films with Low Thermal Coefficient of Resistivity Obtained via Magnetron Deposition |
title_short | Amorphous/Nanocrystalline High-Entropy CoCrFeNiTi(x) Thin Films with Low Thermal Coefficient of Resistivity Obtained via Magnetron Deposition |
title_sort | amorphous/nanocrystalline high-entropy cocrfeniti(x) thin films with low thermal coefficient of resistivity obtained via magnetron deposition |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10343313/ https://www.ncbi.nlm.nih.gov/pubmed/37446519 http://dx.doi.org/10.3390/nano13132004 |
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